Product ID:50-363 BLACK STENCIL AEROSOL, #37038
MSDS Date:06/05/1992
FSC:7510
NIIN:00-224-6734
MSDS Number: CFMYJ

NILES CHEMICAL PAINT CO

225 FORT STREET
NILES, MI 49120
US

Emergency Phone: 219-236-5856

Info Phone: 616-683-3377

Preparer: MICHAEL LICHATOWICH

Cage: 02388

NILES CHEMICAL PAINT

307 NILES, MI 49120 US

Telephone: 616-683-3377/219-236-5856

Cage: 02388

TOLUENE (SARA 313) (CERCLA) (VP = 22 @ 20C

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 11.0%

OSHA PEL 200 PPM

ACGIH TLV: 100 PPM/STEL 150

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ALKYD RESIN

CAS: 66070-60-8

Fraction By Weight: 6.0%

XYLENE (SARA 313) (CERCLA) (VP = 7 @ 20C

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 5.0%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM/STEL 150

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

COBALT COMPOUNDS (SARA 313)

CAS: 7440-48-4

RTECS: GF8750000

Fraction By Weight: <1.0%

OSHA PEL 0.1 MG/M3

ACGIH TLV: 2.0 MG/M3

PROPRIETARY INGREDIENT

Fraction By Weight: BALANCE

VOC = 5.24 LB/GL

RTECS: 9999999VO

OSHA PEL NOT RELEVANT

ACGIH TLV: NOT RELEVANT

AEROSOL PROPELLANT (VP = 70 LBS PSI @ 20C

CAS: 68476-86-8

Fraction By Weight: 30.0%

ACGIH TLV: 900 PPM

ACETONE (SARA 313) (CERCLA) (VP = 266 @ 77F

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 23.0%

OSHA PEL 1000 PPM

ACGIH TLV: 750PPM/STEL 100

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

MINERAL SPIRITS

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 2.0%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

METHYL ISOBUTYL KETONE (HEXONE) (SARA 313) (CERCLA) (VP =

CAS: 108-10-1

RTECS: SA9275000

Fraction By Weight: 2.0%

OSHA PEL 100 PPM

ACGIH TLV: 50 PPM/STEL 75

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

BLACK PIGMENT

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 1.0%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: IRRITATION, TEARING, REDNESS,
BLURRED VISION. SKIN: REDNESS, IRRITATION, DEFATTING, DERMATITIS.
INHAL: IRRITATION, CNS DEPRESSION, (DIZZY, DROWSY, WEAK, FATIGUE,
CONFUSED), NAUSEA, HEADACHE, VERT IGO, UNCONSCIOUSNESS,
ASPHYXIATION. INGEST: IRRITATION, ABDOMINAL PAIN, NAUSEA, VOMITING,
DIARRHEA. CHRONIC: *
Effects of Overexposure:* UNCONSCIOUSNESS, COMA, DEATH, NARCOSIS,
INCOHERENCE, CORNEAL VACUOLIZATION, ANOREXIA, EUPHORIA,
NERVOUSNESS, INSOMNIA, PARESTHESIA, PHOTOPHOBIA. TARGETS: RESP
SYSTEM, SKIN, LUNGS, EYES, CNS, GI T RACT, BLOOD, LIVER & KIDNEYS.

First Aid:INHAL: IMMED GET FRESH AIR. IF NOT BREATHING GIVE ARTIF RESP.
GET IMMED MED AID. SKIN: IMMED WASH W/SOAP & WATER. REMOVE CONTAM
CLOTHES, WASH BEFORE REUSE, GET IMMED MED AID. EYE: IMMED FLUSH
W/LOTS W ATER >15 MIN. LIFT LIDS. GET IMMED MED AID. NO CONTACTS.
INGEST: DRINK 1-2 GLASSES WATER. DONT INDUCE VOMITING. CALL
DR/POISON CONTROL IMMEDIATELY. TREAT SYMPTOMS.

Flash Point Method:TCC
Flash Point:-99F,-73C
Autoignition Temp:Autoignition Temp Text:NE
Lower Limits:0.8
Upper Limits:12.0
Extinguishing Media:DRY CHEMICAL, FOAM, CO2.
Fire Fighting Procedures:USE SCBA W/FULL FACE PIECE IN POSITIVE
PRESSURE MODE/PROTECTIVE CLOTHES. USE WATER TO COOL CLOSED
CONTAINERS. PREVENT PRESSURE BUILD-UP/AUTOIGNIT/EXPLOSION.
Unusual Fire/Explosion Hazard:KEEP CNTNR TIGHTLY CLSD. VAPORS
>AIR/TRAVEL TO IGNITS/FLASH BACK CLSD CNTNR MAY EXPLODE W/HIGH
HEAT. APPLIC TO HOT SURFACES REQ SPEC PRECAUTIONS DECOMP PROD HAZ

Spill Release Procedures:REMOVE IGNITS. AVOID VAPOR BREATHING/SKIN
CONTACT. ABSORB/SHOVEL INTO DRUMS AND DISPOSE. DIKE.

Handling and Storage Precautions:DON'T STORE IN HIGH HEAT/NEAR IGNITS.
KEEP CONTAINER CLOSED WHEN NOT IN USE. AVOID ROUGH HANDLING.
Other Precautions:CONTAINERS HAZARDOUS WHEN EMPTY. DON'T WELD/FLAME CUT
ON EMPTY DRUM. SHOCK FROM DROPPING MAY SPLIT CONTAINER.

Respiratory Protection:WEAR APPROPRIATE PROPERLY FITTED HALF MASK OR
FULL FACEPIECE RESPIRATOR, NIOSH/MSHA APPROVED.
Ventilation:SUFFICIENT.
Protective Gloves:CHEMICAL RESISTANT.
Eye Protection:CHEM GOGGLES/SAFETY GLASSES/FACE SHLD.
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING.
Work Hygienic Practices:WASH HANDS BEFORE EATING/SMOKING/USING
RESTROOM. REMOVE CONTAM CLOTHES TO AVOID FLAMMABILITY HAZARD. WASH
BEFORE REUSE.
Supplemental Safety and Health
NK

Boiling Pt:B.P. Text:-10 TO 330F
Decomp Temp:Decomp Text:NE
Vapor Density:>AIR.
Spec Gravity:0.773
pH:NA
Viscosity:55 #17
Evaporation Rate & Reference:SLOWER THAN ETHER.
Solubility in Water:SLIGHT.
Appearance and Odor:LIQUID, ODOR OF SOLVENT.
Percent Volatiles by Volume:91.33
Corrosion Rate:MINIMAL

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS & ACIDS.
Stability Condition to Avoid:HIGH TEMPERATURES, SHOCK FROM DROPING.
Hazardous Decomposition Products:CARBON MONOXIDE &/OR CARBON DIOXIDE.

Waste Disposal Methods:ACCORDING TO FEDERAL, STATE, LOCAL REGS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.